Title
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Development of an Integrated Structure for the Tri-Generation
of Power, Liquid Carbon Dioxide, and Medium Pressure Steam
Using a Molten Carbonate Fuel Cell, a Dual Pressure
Linde-Hampson Liquefaction Plant, and a Heat Recovery
Steam Generator
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Abstract
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Due to the increase in energy consumption and energy prices, the reduction in fossil fuel
resources, and increasing concerns about global warming and environmental issues, it is necessary to
develop more efficient energy conversion systems with low environmental impacts. Utilizing fuel
cells in the combined process is a method of refrigeration and electricity simultaneous production
with a high efficiency and low pollution. In this study, a combined process for the tri-generation
of electricity, medium pressure steam, and liquid carbon dioxide by utilizing a molten carbonate
fuel cell, a dual pressure Linde-Hampson liquefaction plant and a heat recovery steam generator is
developed. This combined process produces 65.53 MW of electricity, 27.8 kg/s of medium pressure
steam, and 142.9 kg/s of liquid carbon dioxide. One of the methods of long-term energy storage
involves the use of a carbon dioxide liquefaction system. Some of the generated electricity is used
in industrial and residential areas and the rest is used for storage as liquid carbon dioxide. Liquid
carbon dioxide can be used for peak shavings in buildings. The waste heat from the Linde-Hampson
liquefaction plant is used to produce the fuel cell inlet steam. Moreover, the exhaust heat of the fuel
cell and gas turbine would be used to produce the medium pressure steam. The total efficiency of
this combined process and the coefficient of performance of the refrigeration plant are 82.21% and
1.866, respectively. The exergy analysis of this combined process reveals that the exergy efficiency
and the total exergy destruction are 73.18% and 102.7 MW, respectively. The highest rate of exergy
destruction in the hybrid process equipment belongs to the fuel cell (37.72%), the HX6 heat exchanger
(8.036%), and the HX7 heat exchanger (6.578%). The results of the sensitivity analysis show that an
increase in the exit pressure of the V1 valve by 13.33% would result in an increase in the refrigeration
energy by 2.151% and a redu
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